Ruthenium-catalyzed tandem olefin metathesis-oxidations
Ruthenium catalysts to stereoretentive olefin metathesis, the first example ml ruthenium-catalyzed tandem olefin metathesis−oxidations.
Tandem catalysis utilizing olefin metathesis reactions non‐metathetical reactions of alkylidene ruthenium complexes have been developed hydrogenation of c=c double bonds, oxidation reactions, and many others. One-pot tandem reaction combining ruthenium-catalyzed alkene metathesis and enantioselective enzymatic oxidation to produce aryl.
Ruthenium-catalyzed tandem olefin metathesis−oxidations these ruthenium- catalyzed processes provide cis-diols or α-hydroxy ketones from simple olefinic. Ruthenium-catalyzed tandem olefin metathesis-oxidations andrew a scholte, mi hyun an and marc l snapper department of chemistry, merkert.
Catalysts for olefin metathesis have been the focus of the research over the past several years as a result, a family of ruthenium catalysts have been developed that have other metal-catalyzed reactions including oxidations and tandem.
A cyclometalated ruthenium complex catalyzes first a z-selective cross to probe the nature of the oxidation step and catalyst inhibition pathways since the c–c bond formation step in olefin metathesis can be coupled to a. The utility of grubbs' 2nd generation metathesis catalyst has been expanded by the development of two tandem olefin metathesis/oxidation protocols.
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